Mebbes Aye, mebbes No. Pollsters struggle with false recall, so that you get folk who say they voted in (say) 2011 but actually didn't, or the other interpretation is that they genuinely do find more folk who voted than didn't, thus oversampling on one part of the population. With online polls I'm inclined to the latter, as they tend to self select volunteers from people who are politically engaged. Having said that, they do see large swings to Yes in the C2D2E percentiles and a better Yes turnout in younger age groups, both of whom will be prevelent in those new voter classes. Also, RIC canvassing returns and registration drives did show strong yes returns amongst that C2D2E sub section of the populace (on the other hand they usually threw up enough DKs so that if they broke No, those impressive yes percentages would be eroded quickly).
More anecdotally, I met a guy on Saturday who'd never voted once in 35 years, pretty much his whole voting eligible life, but had registered with the intention of voting No. He didn't particularly care who ran the UK or how they did it, just so long as there was a UK. Takes all sorts.
So yeah, the official pollsters do see positive news for Yes in terms of those groups who likely make up large chunks of the newely registered voters, and this is somewhat backed up by the RIC canvassing, but I'll bet it's bloody fragile and while there is a probability that new voters will swing to Yes, there is only limited data to support that and enough uncertainty for me to make it more a matter of faith than fact.