St. Mirren were the first team in British football (possibly world football) to score 3 penalties in one game.
Dave "Killer" Lindsay scoring all three in a match in 1904 vs.....Rangers (1872-2012)! Saints won 5-4.
Rangers also scored a penalty and missed another and apparently is the only match in Scottish league history in which 5 penalties were awarded (although CraigKillie might be able to confirm/refute that).